-
- 大高 敦
- 大阪工業大学工学部応用化学科
書誌事項
- タイトル別名
-
- Catalytic Activity of Linear Polystyrene-Stabilized Metal Nanoparticles in Water
- チョクサ ポリスチレン オ アンテイカザイ ト スル キンゾク ナノ リュウシ ノ スイチュウ ニ オケル ショクバイ サヨウ
この論文をさがす
抄録
<p>Linear polystyrene was suitable as a stabilizer for metal nanoparticles. Transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma-atomic emission spectrometry (ICP-AES) were used to characterize the metal nanoparticles supported by polystyrene. Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs), which prepared by thermal decomposition of Pd(OAc)2 have high catalytic activity and reusability for several carbon-carbon coupling reactions in water. Linear polystyrene-stabilized Pt nanoparticles (PS-Pt(0)NPs) exhibited high catalytic activity for aerobic alcohol oxidation, hydrogen-transfer reduction, and indole synthesis. The reversible transfer of palladium species between reaction medium (water) and stabilizer (polystyrene) was confirmed for several reactions. For Hiyama coupling reaction, the catalytic activity of PdO nanoparticles (Pd(II) species) was much higher than that of Pd nanoparticles (Pd(0) species).</p>
収録刊行物
-
- 有機合成化学協会誌
-
有機合成化学協会誌 74 (12), 1206-1216, 2016
公益社団法人 有機合成化学協会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282680315605120
-
- NII論文ID
- 130005251192
-
- NII書誌ID
- AN0024521X
-
- ISSN
- 18836526
- 00379980
-
- NDL書誌ID
- 027791228
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可