カルコゲン原子複合導入による共役系分子の合成と分子構造

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タイトル別名
  • Synthesis and Molecular Structures of π-Conjugated Systems Containing Chalcogen Atoms
  • カルコゲン ゲンシ フクゴウ ドウニュウ ニ ヨル キョウヤクケイ ブンシ ノ ゴウセイ ト ブンシ コウゾウ
  • Synthesis and Molecular Structures of ^|^pi;-Conjugated Systems Containing Chalcogen Atoms

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説明

Recently, from materials science viewpoint, development of chalcogen-containing π-conjugated systems is much attractive because of their unique photochemical and electronic properties. We have studied new methods for the highly regio- and stereoselective introduction of group 16 heteroatom moieties into unsaturated bonds, i.e., photoinduced radical reactions and transition-metal-catalyzed reactions. Therefore, applications of these methods to construction of chalcogen-containing π-conjugated systems are of great importance because these approaches may lead to discover of new functional materials.<br>This review deals with the introduction of chalcogeno groups into acetylene derivatives bearing redox or photochemical properties such as ferrocene, porphyrin, and diethynylbenzene derivatives.

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