Cross-coupling of Aryl Sulfides Powered by N-Heterocyclic Carbene Ligands
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- Yorimitsu, Hideki
- Department of Chemistry, Graduate School of Science, Kyoto University
書誌事項
- タイトル別名
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- Cross-coupling of Aryl Sulfides Powered by <i><b>N</b></i>-Heterocyclic Carbene Ligands
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説明
<p>Cross-coupling reactions of aryl sulfides are more difficult than they look. We have disclosed that transition metal-NHC complexes allow us to efficiently use a wide range of aryl sulfides as electrophilic coupling partners in various cross-coupling reactions and have thus significantly expanded the scope of aryl sulfides available for the cross-coupling technology. Newly introduced nucleophilic partners include arylzinc reagents, Grignard reagents such as alkynylmagnesium species, amines, ketimines, and diborons to achieve Negishi-type coupling, Kumada-Tamao-Corriu-type coupling, Buchwald-Hartwig-type amination, Buchwald-Hartwig-Miura-type carbonyl α-arylation, and Miyaura-type borylation, respectively. These cross-coupling reactions are particularly advantageous when combined with sulfur-specific transformations to prepare organosulfur substrates. Through the development of catalytic transformations of C-S bonds, sulfur-based organic synthesis has come to complement conventional halogen-based organic methodology.</p>
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 74 (11), 1119-1127, 2016
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680316758400
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- NII論文ID
- 130005433319
- 40021003392
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 027740551
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- 本文言語コード
- en
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- 資料種別
- journal article
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