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- 瀧本 真徳
- 独立行政法人理化学研究所 侯有機金属化学研究室
書誌事項
- タイトル別名
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- Transition Metal-Catalyzed Carboxylation of Unsaturated Organic Compounds under an Atmosphere of CO<sub>2</sub>
- センイ キンゾク ショクバイ オ リヨウ シタ ニサンカ タンソ ニ ヨル フホウワ ユウキブツ ノ カルボキシルカ ハンノウ
- Transition Metal-Catalyzed Carboxylation of Unsaturated Organic Compounds under an Atmosphere of CO2
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The use of carbon dioxide as a low-cost and inherently renewable C1 building block for the synthesis of value-added fine chemicals is of great importance and has been attracted increasing interest. Especially, development of efficient methods to incorporate carbon dioxide into organic compounds forming robust carbon-carbon bonds is challenging issue. For such reactions, various carboxylation reactions using carbon dioxide as a “carboxyl unit” to synthesize carboxylic acids have been realized recently by using transition-metal complexes to activate carbon dioxide. In those examples, specifically, unsaturated compounds having carbon-carbon multiple bonds, such as alkynes, dienes, allenes, and aromatic compounds, have been used as good substrates. In this review article, transition-metal-promoted or -catalyzed carboxylation reactions of unsaturated compounds using carbon dioxide as the building block of carboxyl group are introduced in a comprehensive manner.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 71 (10), 1020-1032, 2013
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680316907392
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- NII論文ID
- 10031203354
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BC3sXhs1Oiu7vI
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 024935654
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可