書誌事項
- タイトル別名
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- Synthesis of P-Chiral Phosphine Ligands and Their Applications in Asymmetric Catalysis
- P-キラルホスフィン ハイイシ ノ ゴウセイ ト ショクバイテキ フセイ ゴウセイ エ ノ リヨウ
- 公開日
- 2014
- DOI
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- 10.5059/yukigoseikyokaishi.72.1084
- 公開者
- 公益社団法人 有機合成化学協会
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説明
This review describes the recent progress of the synthesis of P-chiral phosphine ligands and their applications in transition-metal-catalyzed asymmetric reactions. Many enantiomerically pure P-chiral phosphine ligands have been prepared by the use of phosphine-boranes as the intermediates. Among the ligands prepared hitherto, the bidentate ligands with tert-butyl groups at the phosphorus atoms exhibit remarkably high enantioinduction ability in many catalytic asymmetric reactions, particularly in rhodium-catalyzed hydrogenations. Both enantiomers of air-stable ligands, QuinoxP* and BenzP*, are produced via (R)- and (S)-tert-butylmethylphosphine-boranes. These two ligands have been successfully used not only in asymmetric hydrogenations but also in enantioselective carbon-carbon or carbon-heteroatom bond-forming reactions. Many other P-chiral phosphine ligands reported since 2001 are also described.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 72 (10), 1084-1096, 2014
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680317214848
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- NII論文ID
- 130004706651
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- NII書誌ID
- AN0024521X
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 025849601
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDLサーチ
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