書誌事項
- タイトル別名
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- Air-Stable Open-shell Organic Molecules: Syntheses of Electronic-Spin Delocalized Neutral Radicals and Dynamic Electronic-Spin Physical Properties
- クウキ チュウ デモ アンテイ ナ カイカクユウキ ブンシ : デンシ スピン ヒキョクザイガタ チュウセイ ラジカル ノ ゴウセイ ト ドウテキ デンシ スピン ブッセイ
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Studies on air-stable organic neutral radicals have a history of about 110 years since the first synthesis of triphenylmethyl radical. Physical properties of organic neutral radicals have given substantial far-reaching effects and inspirations for development of molecule-based functionality materials. For the last two decades, we have designed and synthesized novel air-stable organic neutral radicals based on phenalenyl known as an odd-alternant hydrocarbon neutral radical. These radicals possess extremely delocalized electronic-spin natures and high redox abilities. Utilization of high redox ability of the radicals for charge-discharge processes has realized new secondary batteries with high discharge capacity exceeding those of the high-performance lithium-ion secondary batteries. In this review, we describe design and synthesis of our phenalenyl-based stable neutral radicals, their dynamic electronic-spin physical properties, and our challenges for application to secondary batteries.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 70 (1), 50-59, 2012
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680318182144
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- NII論文ID
- 10030480918
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BC38XitFaqsLs%3D
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 023403089
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可
