書誌事項
- タイトル別名
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- Development of Axially Chiral Dicarboxylic Acid Catalyzed Asymmetric Transformations
- ジク フセイ ジカルボンサン オ モチイタ ショクバイテキ フセイ ゴウセイホウ ノ カイハツ
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In the past decade, chiral Brønsted acid catalysis has become a leading tool to achieve catalytic asymmetric transformations. As a source of Brønsted acids, poorly acidic hydrogen bonding donors like (thio)ureas and alcohols had been used in the early study, and strongly acidic phosphoric acids then emerged as an indispensable option. We became interested in the use of chiral carboxylic acids, as they have a distinct acidity which cannot be provided by other Brønsted acids. To this end, we developed axially chiral dicarboxylic acids bearing two carboxylic acids at the 2,2’-positions of a binaphthyl unit, and succeeded in applying these catalysts to a variety of asymmetric transformations.
収録刊行物
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- 有機合成化学協会誌
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有機合成化学協会誌 71 (5), 472-479, 2013
公益社団法人 有機合成化学協会
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詳細情報 詳細情報について
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- CRID
- 1390282680318312576
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- NII論文ID
- 10031171538
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- NII書誌ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BC3sXosVOrtrk%3D
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- ISSN
- 18836526
- 00379980
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- NDL書誌ID
- 024663895
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可