n-Paraffineの臨界点及び沸点について

DOI

書誌事項

タイトル別名
  • A note on the Critical Point and the Boiling Point of n-Paraffines

抄録

A hole theory of liquid paraffines is developed to obtain a relationship between the critical point and the carbon number n of molecules. The theory of the zeroeth approximation for the lattice liquid composed of single-site holes and n-sites molecules leads us to the following results which coincide with the experimental data.<BR>(i) The recipocal of the critical temperatura should increase linearly with is reasing the quantity, {(1/2n) + (1/√n)}.<BR>(ii) The Kammelingh-Onnes constant should increase from 2.6 to 3.0 with increasing the carbon number. (The experimental values increase from 3.4 to 3.9) <BR>(iii) The product of n and the critical pressure should be proportional to the critical temperature.<BR>A linear relation holds too between the reciprocal of the boiling point and {(1/2n) + (1/√n)}, with good accuracy.

収録刊行物

  • 物性論研究

    物性論研究 1954 (75), 73-80, 1954

    物性研究・電子版 編集委員会

詳細情報 詳細情報について

  • CRID
    1390282680350983424
  • NII論文ID
    130004021317
  • DOI
    10.11177/busseiron1943.1954.75_73
  • ISSN
    18837808
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

問題の指摘

ページトップへ