n-Paraffineの臨界点及び沸点について
書誌事項
- タイトル別名
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- A note on the Critical Point and the Boiling Point of n-Paraffines
抄録
A hole theory of liquid paraffines is developed to obtain a relationship between the critical point and the carbon number n of molecules. The theory of the zeroeth approximation for the lattice liquid composed of single-site holes and n-sites molecules leads us to the following results which coincide with the experimental data.<BR>(i) The recipocal of the critical temperatura should increase linearly with is reasing the quantity, {(1/2n) + (1/√n)}.<BR>(ii) The Kammelingh-Onnes constant should increase from 2.6 to 3.0 with increasing the carbon number. (The experimental values increase from 3.4 to 3.9) <BR>(iii) The product of n and the critical pressure should be proportional to the critical temperature.<BR>A linear relation holds too between the reciprocal of the boiling point and {(1/2n) + (1/√n)}, with good accuracy.
収録刊行物
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- 物性論研究
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物性論研究 1954 (75), 73-80, 1954
物性研究・電子版 編集委員会
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詳細情報 詳細情報について
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- CRID
- 1390282680350983424
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- NII論文ID
- 130004021317
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- ISSN
- 18837808
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可