A note on the Critical Point and the Boiling Point of n-Paraffines
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- Kurata Michio
- 京都大学工学部工業化学教室
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- Ishida Shin-ichi
- 旭ダウ株式会社延岡工場
Bibliographic Information
- Other Title
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- n-Paraffineの臨界点及び沸点について
Abstract
A hole theory of liquid paraffines is developed to obtain a relationship between the critical point and the carbon number n of molecules. The theory of the zeroeth approximation for the lattice liquid composed of single-site holes and n-sites molecules leads us to the following results which coincide with the experimental data.<BR>(i) The recipocal of the critical temperatura should increase linearly with is reasing the quantity, {(1/2n) + (1/√n)}.<BR>(ii) The Kammelingh-Onnes constant should increase from 2.6 to 3.0 with increasing the carbon number. (The experimental values increase from 3.4 to 3.9) <BR>(iii) The product of n and the critical pressure should be proportional to the critical temperature.<BR>A linear relation holds too between the reciprocal of the boiling point and {(1/2n) + (1/√n)}, with good accuracy.
Journal
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- Busseiron Kenkyu
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Busseiron Kenkyu 1954 (75), 73-80, 1954
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Details 詳細情報について
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- CRID
- 1390282680350983424
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- NII Article ID
- 130004021317
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- ISSN
- 18837808
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed