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OLIGOMERIZATION OF ETHENE OVER SEVERAL CATALYST BEDS CONSISTING OF BOTH Ni/SiO<SUB>2</SUB>·Al<SUB>2</SUB>O<SUB>3</SUB> AND BPO<SUB>4</SUB>
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- SAKAGUCHI TOMOYA
- Department of Applied and Environmental Chemistry, Kitami Institute of Technology
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- MITA SHINGO
- Department of Applied and Environmental Chemistry, Kitami Institute of Technology
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- MATSUI EMIKO
- Department of Applied and Environmental Chemistry, Kitami Institute of Technology
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- TAKAHASHI MOTOI
- Department of Applied and Environmental Chemistry, Kitami Institute of Technology
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- OKAZAKI NORIYASU
- Department of Applied and Environmental Chemistry, Kitami Institute of Technology
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- TADA AKIO
- Department of Applied and Environmental Chemistry, Kitami Institute of Technology
Bibliographic Information
- Other Title
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- OLIGOMERIZATION OF ETHENE OVER SEVERAL CATALYST BEDS CONSISTING OF BOTH Ni/SiO<SUB>2</SUB>·Al<SUB>2</SUB>O<SUB>3</SUB> AND BPO<SUB>4</SUB>
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Description
The oligomerization of ethene was investigated over several catalysts involving Ni/SiO2·Al2O3(Ni/SA) and BPO4. The oligomerization of ethene activity of SA or BPO4 was very low, while that of Ni/SA was very high. Butene was predominantly observed over Ni/SA, while no product was observed over BPO4. Combined use of Ni/SA and BPO4 was more effective for promoting the ethene oligomerization than Ni/SA, especially for increasing C6 fraction. 1-Butene as C4 products in the ethene oligomerization was mainly obtained in the presence of Ni/SA alone, while an equilibrium mixture of n-butene was formed using Ni/SA and BPO4 together, suggesting that the isomerization of n-butene formed from ethene occurs over BPO4.
Journal
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- Phosphorus Research Bulletin
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Phosphorus Research Bulletin 14 (0), 129-134, 2002
Japanese Association of Inorganic Phosphorus Chemistry
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Details 詳細情報について
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- CRID
- 1390282680440784384
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- NII Article ID
- 130004654432
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- COI
- 1:CAS:528:DC%2BD3sXislSqtbs%3D
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- ISSN
- 09184783
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- Text Lang
- en
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- Data Source
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- JaLC
- Crossref
- CiNii Articles
- OpenAIRE
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- Abstract License Flag
- Disallowed
