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Measures for the Stability of Carbocations and Carbanions in Solutions
Bibliographic Information
- Other Title
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- 溶液中におけるカルボカチオンおよびカルボアニオンの安定性の尺度
Description
The stability of ions in solutions is dependent on the solvation effect, which is governed by the interaction properties of solvents. However, the stability of carbocations and carbanions in organic solvents has been quantitatively estimated by using of the stability scales in aqueous solvents. Therefore, the stability scales in aqueous solvents cannot always successfully be applied to the estimation of the stability in organic solvents . This time, we have comparatively examined the stability scales for carbocations and carbanions in organic solvents and in aqueous solvents on the basis of those in gas phase and solvation energies in the solvents.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 55 (0), 21-21, 2005
The Society of Physical Organic Chemistry, Japan
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Details 詳細情報について
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- CRID
- 1390282680530567936
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- NII Article ID
- 130004646353
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- Article Type
- journal article
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- Data Source
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- JaLC
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed