Measures for the Stability of Carbocations and Carbanions in Solutions

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Other Title
  • 溶液中におけるカルボカチオンおよびカルボアニオンの安定性の尺度

Description

The stability of ions in solutions is dependent on the solvation effect, which is governed by the interaction properties of solvents. However, the stability of carbocations and carbanions in organic solvents has been quantitatively estimated by using of the stability scales in aqueous solvents. Therefore, the stability scales in aqueous solvents cannot always successfully be applied to the estimation of the stability in organic solvents . This time, we have comparatively examined the stability scales for carbocations and carbanions in organic solvents and in aqueous solvents on the basis of those in gas phase and solvation energies in the solvents.

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Details 詳細情報について

  • CRID
    1390282680530567936
  • NII Article ID
    130004646353
  • DOI
    10.11494/kisoyuki.55.0.21.0
  • Data Source
    • JaLC
    • CiNii Articles
    • KAKEN
  • Abstract License Flag
    Disallowed

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