Electron Transfer Reduction of Fluorinated Fullerenes

Ohkubo Kei, Taylor Roger, Boltalina Olga V., Fukuzumi Shunichi

doi:10.11494/kisoyuki.53.0.59.0

Bibliographic Information

Other Title

フッ素化フラーレンの電子移動還元反応

Abstract

Electron transfer reduction of C₆₀F₁₈ to the defluorinated anion, C₆₀F₁₇^- occurs efficiently by a relatively weak one-electron reductant, p-chloranil radical anion; the one-electron reduction potential of C₆₀F₁₈ is evaluated as 0.04 V (vs. SCE) by comparison of the rate constant for electron transfer from 10,10'-dimethyl-9,9',10,10'-tetrahydro-9,9'-biacridine to C₆₀F18 with those of other one-electron reductants. Electron transfer reduction properties of C₆₀F₃₆ are also reported.

Journal

Abstracts of Symposium on Physical Organic Chemistry

Abstracts of Symposium on Physical Organic Chemistry 53 (0), 59-59, 2003

The Society of Physical Organic Chemistry, Japan

Keywords

Details 詳細情報について

CRID: 1390282680530651264

NII Article ID: 130005011330

DOI: 10.11494/kisoyuki.53.0.59.0

Data Source

JaLC
CiNii Articles

Abstract License Flag: Disallowed

Export