Kinetic Study of Hydrogen-Transfer Reaction of Acyloin

DOI

Bibliographic Information

Other Title
  • アシロイン水素移動反応の速度論的研究

Abstract

Hydrogen-transfer reactions of acyloin derivatives were studied in order to understand how and when solvation-desolvation takes place in the reactions in solution. Acyloin is expected to isomerize via intramolecular hydrogen transfer under acidic and basic conditions. The mechanism of the hydrogen transfer was analyzed on the basis of the equilibrium constants and the reaction rates of benzoin derivatives under these conditions.

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Keywords

Details 詳細情報について

  • CRID
    1390282680530825728
  • NII Article ID
    130004645831
  • DOI
    10.11494/kisoyuki.2011.0.317.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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