Photoinduced electron-transfer reaction of 1,2-bis(alpha-styryl)benzene: generation and kinetic analyses of o-quinodimethane
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- Ikeda Teruyo
- Grad. Sch. of Science, Tohoku Univ.
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- Takahashi Yasutake
- Faculty of technology, Mie Univ.
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- Akagi Megumi
- Grad. Sch. of Science, Tohoku Univ.
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- Kamata Masaki
- Faculty of Education and Human Sciences, Niigata Univ.
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- Terou Shyouzou
- Institute of Multidisciplinary Research for Advanced Materials, Tohoku univ.
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- Myashi Tsutomu
- Grad. Sch. of Science, Tohoku Univ.
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- Ueda Minoru
- Grad. Sch. of Science, Tohoku Univ.
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- Ikeda Hiroshi
- Grad. Sch. of Science, Tohoku Univ.
Bibliographic Information
- Other Title
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- 1,2-ビス(α-スチリル)ベンゼンの光誘起電子移動反応: オルトキノジメタンの生成と速度論的解析
Abstract
Photoinduced electron-transfer reactions of 1,2-bis(α-styryl)benzene (1) gave the corresponding cyclized product, an o-quinodimethane derivate (2). Time-resolved absorption spectroscopy upon laser flash photolysis of 1 confirmed that 2 radical cation decayed and 2 rose with nearly the same rate constants. These results provided the first agreement in kinetics between a reactive radical cation intermediate and the corresponding neutral species formed by back electron transfer.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 55 (0), 36-36, 2005
The Society of Physical Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680530893824
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- NII Article ID
- 130004646369
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed