Chemical Functionalization of Endohedral Metallofullerene M2@C80
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- Yamada Michio
- Univ. of Tsukuba
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- Wakahara Takatsugu
- Univ. of Tsukuba
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- Nakahodo Tsukasa
- Univ. of Tsukuba
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- Tsuchiya Takahiro
- Univ. of Tsukuba
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- Akasaka Takeshi
- Univ. of Tsukuba
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- Maeda Yutaka
- Tokyo Gakugei univ.
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- Markus Waelchli
- Bruker Biospin
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- Yoza Kenji
- Bruker AXS
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- Ernst Horn
- Rikkyo univ.
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- Mizorogi Naomi
- IMS
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- Kobayashi Kaoru
- IMS
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- Nagase Shigeru
- IMS
Bibliographic Information
- Other Title
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- 金属内包フラーレンM2@C80の化学修飾
Description
Endohedral metallofullerene M2@C80 have attracted special attention for the dynamics of the encapsulated metal atoms because of their three-dimensional random motion inside the fullerene cage. It is proposed that such a dynamics are derived from the electrostatic potential inside the cage. If we can change the electrostatic potential, it may be possible to control the motion of encapsulated metal atoms. In this work, we synthesized and characterized the silylated M2@C80 by addition of the disilirane and the 1,3-dipolar cycloadduct of M2@C80 by addition of the azomethine ylide. It is revealed that the encapsulated metal atoms show two-dimensional circular motion inside the silylated M2@C80 and locate at the stable site on the mirror plane position inside the 1,3-dipolar cycloadduct.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 55 (0), 56-56, 2005
The Society of Physical Organic Chemistry, Japan
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Details 詳細情報について
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- CRID
- 1390282680530940800
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- NII Article ID
- 130004646391
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed