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Reaction of a Disilyne with Organolithium Reagents
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- YAMAGUCHI Torahiko
- Department of Chemistry, Graduate school of pure and applied Sciences, University of Tsukuba
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- SUNAKO Mayumi
- Department of Chemistry, Graduate school of pure and applied Sciences, University of Tsukuba
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- ICHINOHE Masaaki
- Department of Chemistry, Graduate school of pure and applied Sciences, University of Tsukuba
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- SEKIGUCHI Akira
- Department of Chemistry, Graduate school of pure and applied Sciences, University of Tsukuba
Bibliographic Information
- Other Title
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- ジシリンと有機リチウム試薬との反応
Description
The reaction of disilyne with methyllithium was examined. The 1,2-addition of methyllithium to disilyne proceeded, and the methyl-substituted disilenyllithium was obtained. The methyl-substituted disilenyllithium was not stable in THF, and gradually isomerized to the hydrogen-substituted silyllithium at room temperature.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 2009 (0), 287-287, 2009
The Society of Physical Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680531453696
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- NII Article ID
- 130004728909
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed
