Supramolecular Assembly Comprised of Face-to-face π/π Interaction

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Bibliographic Information

Other Title
  • face-to-face型π－π相互作用を利用した超分子構築

Abstract

We here report crystal engineering using face-to-face pi-pi interaction of anthracene moieties. Its interaction energy is estimated about 8 kcal/mol, which is comparative to that of hydrogen bond. First, we examine solvent effect in crystallization of 1,3-diphenyl-2-propanol. When benzene was used as solvent, polymorph was obtained, probably because benzene disturbed the pi-pi interaction between anthracenes. Next, crystalline inclusion host compounds bearing three-fold axis and three anthracene planes are designed and synthesized. It is revealed that those compounds include various guest component.

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Details 詳細情報について

  • CRID
    1390282680531503232
  • NII Article ID
    130004644613
  • DOI
    10.11494/kisoyuki.16.0.1073.0
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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