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Hyperchromic Effect of Silyl Groups on the UV-Visible Spectrum of Azobenzene
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- Ishida Shintaro
- Graduate School of Science, Tohoku University
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- Fujino Mitsunari
- Graduate School of Engineering, Gunma University
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- Ishikawa Michiko
- Graduate School of Engineering, Gunma University
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- Tanaka Hiroshi
- Graduate School of Engineering, Gunma University
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- Yamaya Akio
- Graduate School of Engineering, Gunma University
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- Kuribara Takayoshi
- Graduate School of Engineering, Gunma University
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- Kyushin Soichiro
- Graduate School of Engineering, Gunma University
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- Matsumoto Hideyuki
- Graduate School of Engineering, Gunma University
Bibliographic Information
- Other Title
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- アゾベンゼンの紫外可視吸収スペクトルに及ぼすシリル基の濃色効果
Description
Azobenzene has extensively been studied as a photo-functional dye. The increase of the molecular extinction coefficient of azobenzene leads to highly photo-sensitive materials. In this study, we synthesized various silyl-substituted azobenzenes and found that the molecular extinction coefficients of these compounds are much larger than that of azobenzene. We discuss these results on the basis of theoretical calculations of molecular orbitals and transition moments.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 2011 (0), 135-135, 2011
The Society of Physical Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680531710336
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- NII Article ID
- 130004645629
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed
