Synthesis and properties of silicon analogs of hipposudoric acid

DOI

Bibliographic Information

Other Title
  • カバの「汗」に含まれるヒポスドール酸のケイ素類縁体の合成と物性

Description

A silicon analog of hipposudoric acid (3,7-di-tert-butyl-5,5-dimethyl-1H-dibenzo[b,d]silole-1,4,6,9(5H)-tetraone) and some related compounds are synthesized. This compound has a silole ring fused with two quinone rings. Because of the structure, their carbonyl groups are forced to close to each other and the molecule has a highly distorted non-planar pi-conjugation system. Redox potentials and electronic absorption as well as photoreactivities of the compounds will be discussed.

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Keywords

Details 詳細情報について

  • CRID
    1390282680531712000
  • NII Article ID
    130004645630
  • DOI
    10.11494/kisoyuki.2011.0.136.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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