Ring-expansion living radical polymerization of cyclic polyolefines derived from nitroxide-based biradicals
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- KAKUYA Ryosuke
- Department of Chemistry, Nagoya University
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- MATSUSHITA Michio M.
- Department of Chemistry, Nagoya University
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- AWAGA Kunio
- RCMS
Bibliographic Information
- Other Title
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- ニトロキシド系ビラジカルを用いた環状ポリオレフィン類のリビングラジカル重合
Abstract
Cyclic polymers are interested in their low melting points, viscosity, etc, in comparison with their corresponding linear chain analogue. On the other hand, physical properties of cyclic polymers have not been investigated widely, because efficient synthetic methods have not been developed. We designed and prepared novel precursor, having two reaction points derived from nitroxide-based diradical, for ring-expansion polymerization of polyolefines. As the result, we succeeded to prepare ring polystylenes using these new precursors. The details of reaction will be discussed with GPS, MALDI-TOF-MS, and some other spectroscopic data.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 2011 (0), 110-110, 2011
The Society of Physical Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680531776768
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- NII Article ID
- 130004645602
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed