Molecular Design of Ionic Liquids for Dynamic Solvent Effect - Pressure Effect on Ionic Liquids

DOI

Bibliographic Information

Other Title
  • 動的溶媒効果を示すイオン液体（媒体）の分子設計－イオン液体と圧力

Description

In general, rearrangement of solvent molecules is more rapid than movement of a reactant solute. However, this relation can be inverted when viscosity of the used solvent drastically increase by applying high pressure. Here we firstly report this phenomenon, known as the dynamic solvent effect, could be observable even in imidazolium ionic liquids. Pressure effect (0.1 M-600 Mpa) on a photoisomerization reaction in an ionic liquid was monitored from the viewpoint of the molecular structure of the salt medium. We would discuss the relation between the dynamic solvent effect and the salt design (side chain structure of the imidazolium cation and anion size).

Journal

Keywords

Details 詳細情報について

  • CRID
    1390282680531807360
  • NII Article ID
    130004646435
  • DOI
    10.11494/kisoyuki.57.0.14.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

Report a problem

Back to top