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Difference between CH/pi inetraction and hydrogen bond: Effects of acidity of C-H bond on the nature of CH/pi interaction
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- Tsuzuki Seiji
- Research Institute of Computational Sciences AIST
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- Fujii Asuka
- Dept. of Chemistry, Graduate School of Sience, University of Tohoku
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- Honda Kazumasa
- RESEARCH INSTITUTE OF INSTRUMENTATION FRONTIER AIST
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- Uchimaru Tadafumi
- Research Institute of Computational Sciences AIST
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- Mikami Masuhiro
- Research Institute of Computational Sciences AIST
Bibliographic Information
- Other Title
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- CH/π相互作用と水素結合の違い：C-H 結合の酸性度が CH/π相互作用に与える影響
Description
The CH/pi interaction has been studied by high-level ab initi calculations and by measurements of IR and UV-Vis spectra. Although the nature of the CH/pi intearction of acidic C-H bonds such as the C-H bond of acetylene may be similar to that of the hydroben bond, the nature of the CH/pi interactions of typical (non-activated, low acidic) C-H bonds are completely different from that of the hydrogen bond.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 18 (0), 72-72, 2006
The Society of Physical Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680532080256
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- NII Article ID
- 130004645172
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed
