Unprecedented Thermal Rearrangement of Push-Pull-Chromophore-[60]Fullerene Conjugates: Formation of Chiral 1,2,9,12-Tetrakisadducts

DOI

Bibliographic Information

Other Title
  • Push-Pull型クロモフォア－[60]フラーレン連結系の新規な熱転位反応: キラルな1,2,9,12-テトラキス付加体の形成

Description

We recently reported the synthesis of push–pull-chromophore-fullerene conjugates by [2+2] cycloaddition of electron-deficient olefins to the electron-rich CC triple bond of donor-substituted alkynylfullerene, followed by cycloreversion. During this work, we encountered an unprecedented thermal rearrangement yielding the formation of C1-symmetric 1,2,9,12-tetrakis-adducts of [60]fullerene, which will be presented.

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Details 詳細情報について

  • CRID
    1390282680532157952
  • NII Article ID
    130004729328
  • DOI
    10.11494/kisoyuki.2010.0.a24.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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