Synthesis of Chiral Cryptand-type Compound fromTripodand-type Ligand and its Inclusion Behavior toward Gest Molecules

DOI

Bibliographic Information

Other Title
  • 新規三脚型配位子から誘導されるキラルクリプタンド型化合物の合成とゲスト分子包摂挙動

Abstract

A chiral tripodand having three binaphthyl moieties and three hydroxyl terminal groups were prepared. The reaction of this tripodand with benzene 1,3,5-tricarboxylic acid chloride gave a cryptand-type caged product. The X-ray structure of the product was measured and confirmed to be caged compound. The caged product formed 1:1 complex with tetraethylaminomium ion selectively among several kinds of ammonium ions. Also, it was found that the caged product can include halogenated carbons by the measurement of elemental analysis and TG-TDA analysis.

Journal

Keywords

Details 詳細情報について

  • CRID
    1390282680532669952
  • NII Article ID
    130004645498
  • DOI
    10.11494/kisoyuki.2008.0.366.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

Report a problem

Back to top