Macrocyclic host consisted of <I>meta</I>-ethynylpyridine as a unit

DOI
  • Kurokawa Hiroyuki
    Graduate School of Pharmaceutical Sciences, University of Toyama
  • Abe Hajime
    Graduate School of Pharmaceutical Sciences, University of Toyama PRESTO, JST
  • Inouye Masahiko
    Graduate School of Pharmaceutical Sciences, University of Toyama

Bibliographic Information

Other Title
  • <I>meta</I>-エチニルピリジンを単位とする大環状オリゴマーの合成と糖認識能

Description

Macrocyclic oligomers consisted of ethynylpyridine units has been developed as artificial host molecules for saccharide recognition. They were synthesized through 4-butoxy-2,6-dibromopyridine as an intermediate, and repeating Sonogashira reaction and Glaser coupling gave the oligomers, which mainly include 9-mer and 12-mer from MS analyses. The 9-mer was examined its saccharide recognition abilities, and induced CD was observed by the addition of octyl glucoside.

Journal

Keywords

Details 詳細情報について

  • CRID
    1390282680533040128
  • NII Article ID
    130004644990
  • DOI
    10.11494/kisoyuki.18.0.231.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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