Studies on the Synthesis of 1,2-Bis(ferrocenyl)diphosphene by Taking Advantage of Kinetic Stabilization

DOI

Bibliographic Information

Other Title
  • 速度論的安定化を利用した1,2-ビス（フェロセニル）ジホスフェンの合成検討

Description

We have already reported the synthesis, properties, and redox behavior of kinetically stabilized ferrocenyldiphosphenes as novel d-π electron conjugated systems containing main group elements. In this presentation, a novel bulky ferrocenyl unit was designed and synthesized for the purpose of the synthesis of a novel 1,2-bis(ferrocenyl)diphosphene derivative. As a result, 1,3-bis(3,5-dimethylphenyl)-2-iodoferrocene has been successfully synthesized as a novel ferrocenyl unit bearing bulky aryl groups at the 1,3-positions.We report here the attempted synthesis of the corresponding 1,2-bis(ferrocenyl)diphosphene bearing the novel ferrocenyl groups.

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Details 詳細情報について

  • CRID
    1390282680533346944
  • NII Article ID
    130004728810
  • DOI
    10.11494/kisoyuki.2009.0.198.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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