reactivity and selectivity of the electrophilic addition to beta-substituted ester enolates

Bibliographic Information

Other Title
  • β置換エステルエノラートへの求電子付加反応における反応性と選択性

Description

reactivity and selectivity of the electrophilic addition to beta-substituted ester enolates have been investigated by both experimental and theoretical method. It has been revealed that a hyperconjugation from beta-substituent to reaction center is strongly affect the reactivity of them and controlled their diastereoselectivity.

Journal

Details 詳細情報について

  • CRID
    1390282680533380736
  • NII Article ID
    130004646074
  • DOI
    10.11494/kisoyuki.2011.0.95.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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