Synthesis and Structures of Transition Metal Complexes with New Tripodal Tetradentate Ligands Bearing Three Thioether Moieties
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- Takeda Nobuhiro
- Gunma University Silicon Center
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- Tanaka Yusuke
- Gunma University
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- Nakamura Tetsu
- Gunma University
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- Imamura Ayako
- Gunma University
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- Tagawa Tomonori
- Gunma University
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- Watanabe Daisuke
- Gunma University
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- Yamamoto Yoko
- Gunma University
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- Unno Masafumi
- Gunma University Silicon Center
Bibliographic Information
- Other Title
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- ３つのチオエーテル部位を有する新規三脚型四座配位子を用いた遷移金属錯体の合成とその構造
Abstract
Transition metal complexes bearing tripodal tetradentate ligands have attracted considerable interest due to their ability for the activation of small molecules, the stabilization of reactive species with unusual electric and geometric structures, catalytic activities, and so on. Although there are many reports on tripodal tetradentate ligands containing amine or phosphine moieties as donors, tripodal tetradentate ligands tethered with three thioether moieties are very rare. In this paper, we present the synthesis of phosphine and silyl ligands tethered with three thioether moieties, P(2-C6H4SR)3 (R = i-Pr, t-Bu) and –Si(2-C6H4CH2SR)3 (R = i-Pr, t-Bu), respectively, and their complexation with transition metals.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 2009 (0), 100-100, 2009
The Society of Physical Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282680533553664
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- NII Article ID
- 130004728704
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed