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Knoevenagel Condensation Catalyzed by a Cationic Hollow Complex
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- Murase Takashi
- School of Engineering, The Univ. of Tokyo
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- Nishijima Yuki
- School of Engineering, The Univ. of Tokyo
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- Fujita Makoto
- School of Engineering, The Univ. of Tokyo CREST
Bibliographic Information
- Other Title
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- カチオン性中空錯体による触媒的Knoevenagel縮合
Description
In this study, we performed Knoevenagel condensation of naphthaldehydes with Meldrum's acid in the presence of a cationic self-assembled coordination cage. The cationic cage accommodating naphthaldehydes promoted nucleophilic attack of Meldrum's acid from the outside of the cage and stabilized anionic intermediates. Because the products are readily replaced with naphthaldehydes and not encapsulated within the cage, the condensation proceeded in a catalytic amount of the cage.
Journal
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- Abstracts of Symposium on Physical Organic Chemistry
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Abstracts of Symposium on Physical Organic Chemistry 2011 (0), 41-41, 2011
The Society of Physical Organic Chemistry, Japan
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Details 詳細情報について
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- CRID
- 1390282680533578624
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- NII Article ID
- 130004645934
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- Text Lang
- ja
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- Data Source
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- JaLC
- CiNii Articles
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- Abstract License Flag
- Disallowed
