Preparation of Visible-Light Responsive Photocatalyst from Complex of Ti<SUP>4+</SUP> with Nitrogen-Containing Ligand

  • SANO Taizo
    National Institute of Advanced Industrial Science and Technology, JAPAN
  • NEGISHI Nobuaki
    National Institute of Advanced Industrial Science and Technology, JAPAN
  • TAKEUCHI Koji
    National Institute of Advanced Industrial Science and Technology, JAPAN
  • MATSUZAWA Sadao
    National Institute of Advanced Industrial Science and Technology, JAPAN

書誌事項

公開日
2003
DOI
  • 10.14853/pcersj.2003f.0.1004.0
公開者
公益社団法人 日本セラミックス協会

説明

The anatase type of TiO2 photocatalyst was synthesized by calcination of complex of Ti4+ with nitrogen-containing ligand. The photocatalyst exhibited high photocatalytic activity and high NOx removal efficiency under both of ultraviolet and visible-light illumination. Conventional TiO2 photocatalyst (ST-01 or P25) did not remove NOx under irradiation of visible light (> 495 nm), while the newly synthesized photocatalyst removed 16 % of NOx, which corresponded to the NOx removal of ST-01 under UV light irradiation (>305 nm). The maximum wavelength at which the photocatalyst worked was 645 nm. The simultaneous doping of N and C atoms into anatase lattice, which is expected from UV-VIS spectroscopy, XRD, and XPS, may be a factor for the visible light absorption and NOx removal activity under wide range of visible light irradiation.

収録刊行物

詳細情報 詳細情報について

  • CRID
    1390282680588305920
  • NII論文ID
    130006967376
  • DOI
    10.14853/pcersj.2003f.0.1004.0
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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