Preparation of organic derivatives of layered perovskite using n-alkylamine layered perovskite intercalation compounds as intermediates

DOI

Bibliographic Information

Other Title
  • n-アルキルアミン層間化合物を中間体として用いた層状ペロブスカイト有機誘導体の合成

Abstract

The alkoxyl derivatives of layered perovskite, H1.8Sr0.8Bi0.2Ta2O7, were prepared using n-alkylamine layered perovskite intercalation compounds as intermediates. After the reaction of n-alkylamine intercalation compound of HST with n-decanol in an autoclave at 150°C the basal spacing increased. Carbon-13 NMR showed the presence of signals due to n-decoxyl groups and downfield shift of a a-carbon signal, indicating of the formation of Ta-O-C bond. These results suggest successful modification of H1.8Sr0.8Bi0.2Ta2O7.

Journal

Details 詳細情報について

  • CRID
    1390282680589522816
  • NII Article ID
    130006968760
  • DOI
    10.14853/pcersj.2003s.0.560.0
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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