Chemical Modification of Diamond Powder Using Photolysis of Perfluoroazooctane
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- NAKAMURA Takako
- National Institute of Advanced Industrial Science and Technology, JAPAN
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- ISHIHARA Masatou
- National Institute of Advanced Industrial Science and Technology, JAPAN
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- OHANA Tsuguyori
- National Institute of Advanced Industrial Science and Technology, JAPAN
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- KOGA Yoshinori
- National Institute of Advanced Industrial Science and Technology, JAPAN
説明
Diamond is a material, which has been widely investigated because of its various unique properties such as electrical, thermal and mechanical properties. Chemical modifications of the diamond surfaces have been expected to lead improvement of its original behavior. We can find recent studies on chemical modification with various organic functional groups on the surface of diamond films and powders terminated with hydrogen or oxygen by using photo- and thermochemical methods. On the other hand, Introduction of substituents containing fluorine atom would result in improvement of the behavior of diamond surfaces, which is enhanced lubricity and stability under extreme conditions. Previously we reported that photolysis of perfluoroazooctane gave perfluorooctyl radicals effectively under mild conditions for perfluoroalkylation of organic compounds. In this paper, we report on a useful method for chemical modification of diamond powders with perfluoroalkyl substituent by using photolysis of perfluoroazooctane under mild condition.
収録刊行物
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- 日本セラミックス協会 年会・秋季シンポジウム 講演予稿集
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日本セラミックス協会 年会・秋季シンポジウム 講演予稿集 2003F (0), 1102-1102, 2003
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390282680590189696
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- NII論文ID
- 130006969413
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
