Catalytic Hypervalent Iodine Oxidations of Phenols Using 4-Iodophenoxyacetic Acid-Oxone System

DOI
  • Yakura Takayuki
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
  • Ozono Ayaka
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
  • Konishi Tatsuya
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
  • Yamauchi Yû
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
  • Tian Yuan
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama
  • Omoto Masanori
    Graduate School of Medicine and Pharmaceutical Sciences, University of Toyama

Bibliographic Information

Other Title
  • 4-ヨードフェノキシ酢酸－オキソン系を用いるフェノール類の触媒的酸化反応

Description

We report here novel hypervalent iodine oxidations of phenols using a catalytic amount of 4-iodophenoxyacetic acid and an equimolar amount or an excess of Oxone (2KHSO5•KHSO4•K2SO4) as a co-oxidant. <BR> This oxidation system has the following features. The first is that reaction proceeds under mild conditions. The second is that Oxone is an inorganic, water-soluble, commercially available, and inexpensive with low toxicity. The third is that solubility of the catalyst in alkaline solution facilitates its recovery.

Journal

Keywords

Details 詳細情報について

  • CRID
    1390282680612110464
  • NII Article ID
    130006997887
  • DOI
    10.14895/hannou.35.0.88.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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