3B01 Mesomorphic and Carrier transport properties of Nikel Phthalocyanine Complexes Bearing Siloxane Moieties

DOI

Bibliographic Information

Other Title
  • 3B01 側鎖末端にシロキサン部位を導入したニッケルフタロシアニン錯体の液晶性と電荷輸送特性(分子配向エレクトロニクス,口頭発表,2015年日本液晶学会討論会)

Search this article

Description

Non-peripherally alkylated liquid crystalline metal-free phthalocyanines (Pc) exhibit good carrier transport properties in their columnar phases at high temperature. However, they crystallize at room temperature and their solubilities are insufficient to forms thin films by a solution process. In this study, we synthesized nikel Pc complexes bearing siloxane moieties. These compounds exhibit columnar phases at room temperature in spite of their bulky siloxane moieties, through nano-segregation between π conjugated cores and siloxane moieties. Moreover these have high solubilities in n-hexane and one of these compounds exhibits ambipolar carrier transport at room temperature.

Journal

Details 詳細情報について

  • CRID
    1390282680663599104
  • NII Article ID
    110010027431
  • DOI
    10.11538/ekitou.2015.0__3b01
  • ISSN
    24325988
    18803490
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

Report a problem

Back to top