On chirality or planality controle in molecular mchanics

Bibliographic Information

Other Title
  • 分子力学法における不斉性・平面性拘束について

Description

We propose a new form of penalty function to constrain molecular structural chirality or planelity in molecular mechanics calculation. By using the signed volume of tetrahedral structure spanned with four unit vectors arround centered chiral carbon atom as a single variable index of the chirality, all chemical bonds are treated as symmetrically equivalent, and any form of single variable function is available for the constraint penalty function. The index of chirality can be extended for the three chemical bond case, and can be used as symmetrical planer constraint penalty functions.

Journal

Details 詳細情報について

  • CRID
    1390282680714522624
  • NII Article ID
    130004575104
  • DOI
    10.11545/ciqs.2012.0.p18.0
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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