3-1-4 Pyrolysis mechanism of lignin dimer models produced from p-coumaryl, coniferyl and sinapyl alcohol

DOI

Bibliographic Information

Other Title
  • 3-1-4 p-Coumaryl, Coniferyl, Sinapyl alcohol 二量体モデルの熱分解反応機構(Session 3-1 熱分解)

Abstract

Bio-oil produced by fast pyrolysis of biomass is considered to be a new resource as a substitute for fuel oil or diesel in many static applications such as boilers, furnaces, engines, and turbines for electricity generation or chemical production. Lignin is the polymerization product of coniferyl, sinapyl and p-coumaryl alcohol. Thus, the polymer consists of phenylpropane units with varying degrees of methoxylation on the aromatic rings. Some researchers have proposed the mechanism of lignin pyrolysis using monomer and dimer models. However, there are no reports using systematical p-coumaryl, coniferyl and sinapyl alcohol dimer models with three principal linkages. These compounds have γ-hydroxymethyl structure and this structural moiety is considered as leaving group. Therefore, it is important to

Journal

Details 詳細情報について

  • CRID
    1390282680788768896
  • NII Article ID
    110009891854
  • DOI
    10.20550/jietaikaiyoushi.23.0_70
  • ISSN
    24238325
    24238317
  • Text Lang
    ja
  • Data Source
    • JaLC
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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