Crystal Structure and Epitaxy of Copper Phthalocyanine on Alkali-halide Substrates(<Special Issue>Organic Crystals)

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  • アルカリハライド基板上での銅フタロシアニンの結晶構造とエピタキシー(<小特集>有機結晶の新展開)
  • アルカリハライド基板上での銅フタロシアニンの結晶構造とエピタキシー
  • アルカリハライド キバン ジョウ デ ノ ドウ フタロシアニン ノ ケッショウ コウゾウ ト エピタキシー

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Abstract

One of the earliest studies of organic epitaxy using vacuum deposition method is on the epitaxial growth of copper phthalocyanine on alkali-halide substrates. In this study, the relation between the epitaxial orientation and the orientation of a phtalocyanine molecule adsorbed on the substrate was discussed. The origin of the epitaxial orientation, however, has not been well-understood, in particular, in the light of lattice matching at the interface. This article reveals that the misunderstanding about the crystal structures of planar phthaocyanines have prevented its understanding. On the basis of the newly solved crystal structure, the lattice matching at the interface and the effect of the orientation of a phthalocyanine molecule on the substrate are discussed.

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