Fe(III)吸着剤による人工廃水からのヒ素(III)の除去および溶出

  • 劉 克俊
    東京大学 21世紀COE機械システムイノベーション (現 蘇州同和資源総合利用有限公司)
  • 藤田 豊久
    東京大学 工学系研究科 地球システム工学専攻
  • 松尾 誠治
    東京大学 工学系研究科 地球システム工学専攻
  • 定木 淳
    東京大学 工学系研究科 地球システム工学専攻
  • 柴山 敦
    秋田大学 工学資源学部 環境物質工学科
  • 中西 康二
    日鉄鉱業株式会社

書誌事項

タイトル別名
  • Removal and Elution of Arsenic (III) ion from Artificial Waste Water by Adsorbent containing Fe (III)
  • Fe 3 キュウチャクザイ ニ ヨル ジンコウ ハイスイ カラ ノ ヒソ 3 ノ ジョキョ オヨビ ヨウシュツ

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抄録

In this study an arsenic plate adsorbent was prepared in two stages. Initially a Fe(III) bearing high molecular solid particle adsorbent was made from a ferric salt. Finally the solid particle was evenly spread on a plastic plate by using a special treating process to become an arsenic plate adsorbent. The mechanism of arsenic adsorption on this adsorbent is a kind of ion exchange process. It can adsorb both arsenic(III) and arsenic(V) from the wasted water. The arsenic removal was about 99%. In a solution contains 20mg/L arsenic at pH6. 99% of arsenic was removed in 2 hours by a l0g/L solid particle adsorbent and the final arsenic concentration was reduced to below 0.05mg/L arsenic. Furthermore, it was found that the re-adjustment of solution pH and temperature might cause the elution of arsenic and let it return back to the solution. The activity of the adsorbent was not reduced after elution. Thus, it can be re-used several times without producing the contaminated mud. The cost of the contaminated mud treatment can be reduced or completely avoided. The recovery and recycling of arsenic metal for re-use are feasible. Under the condition of high alkali solution (pH13), 363K and 2 hours, a plate adsorbent was re-used for five cycles with the arsenic elution was 80-99%.

収録刊行物

  • 資源と素材

    資源と素材 121 (6), 240-245, 2005

    一般社団法人 資源・素材学会

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