イオン対抽出-けい光定量における発けい光キレート化剤としてのルモガリオンとカルコンの比較および第3級アミンの定量への応用

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書誌事項

タイトル別名
  • Comparison between Lumogallion and Calcon on Ion Pair Extraction-Fluorometry and the Application for Determination of Tertiary Amines
  • イオンツイ チュウシュツ ケイコウ テイリョウ ニ オケル ハツケイコウ キレ

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説明

Fluorescent intensity of lumogallion, a fluorescent complex by the addition of aluminium ion after association with primary, secondary and tertiary n-alkylamines was compared with that of calcon. In the result, lumogallion formed a well extractable complex with tertiary amines but merely produced a complex with secondary amines and not produced a complex with primary amines. This method was applied to the determination of local anesthetics and psychotropic agents. Carpipramine, opipramol, benactyzine, chlorpromazine, procaine and lidocaine could be determined in the range of 2×10-8-10-9 mol/ml sample (ca. 8×10-10-10-11 mol/ml measurement solution). Primary and secondary amines at least less than equal molar in the sample did not interfer the determination. Recoveries of carpipramine and chlorpromazine in milk were 99 to 103%.

収録刊行物

  • 薬学雑誌

    薬学雑誌 104 (4), 351-355, 1984

    公益社団法人 日本薬学会

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