New Development of Photo-induced Electron Transfer Reaction and Total Synthesis of Natural Product

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  • HAMADA Tatsuo
    Graduate School of Pharmaceutical Sciences, Hokkaido University

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  • 新しい光電子移動反応の展開から天然物合成研究まで
  • アタラシイ コウデンシ イドウ ハンノウ ノ テンカイ カラ テンネンブツ ゴウセイ ケンキュウ マデ

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Abstract

  Some new developments of photochemical one-electron transfer reactions are described, and reaction mechanisms are discussed. Application of catalytic photoelectron transfer (photo-cleavage of sulfonamide) to the total synthesis of (−)-cannabisativine is also reported. In order to develop new synthetic methodology, conformational analysis of macrolide seco-acid is presented, and the design and application of seco-acids to the first total synthesis of lankanolide is also disclosed.<br>

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  • YAKUGAKU ZASSHI

    YAKUGAKU ZASSHI 125 (1), 1-16, 2005-01-01

    The Pharmaceutical Society of Japan

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