Diphenylethane系化合物の立体構造

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書誌事項

タイトル別名
  • Steric Constitution of Diphenylethane Analogues
  • Diphenylethaneケイ カゴウブツ ノ リッタイ コウゾウ

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抄録

The structures of β-(3-hydroxy-4-methoxyphenyl) ethylbenzene (I) and 1, 2-bis (3-hydroxy-4-methoxyphenyl) ethane (II) were determined by single-crystal X-ray diffraction method. The sweet compound I was synthesized as the essential structure for the sweet taste of phyllodulcin, while the tasteless compound II was synthesized as the chemical modification product of I. Between the structures of I and II, there are distinct differences in the dihedral angles made by the two planes of phenyl group and in the conformation of ethylene bridges. The structure of II is similar in conformation to that of dibenzyl while that of I is not.

収録刊行物

  • 薬学雑誌

    薬学雑誌 97 (11), 1180-1188, 1977

    公益社団法人 日本薬学会

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