Pyridinium Ylideを用いるα-Pyridone誘導体の合成

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タイトル別名
  • Synthesis of α-Pyridone Derivatives with Pyridinium Ylide
  • Pyridinium ylide オ モチイル アルファ-Pyridone ユウドウタイ ノ ゴウセイ
  • Synthesis of α-Pyridone Derivatives with Pyridinium Ylide

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抄録

Synthetic methods for α-pyridone, such as those of Thesing, et al. and Kronke, et al. were examined and (3-indolyl) pyridin-2 (1H)-one derivatives were synthesized by the reaction of indole compounds having α, β-unsaturated ketone in the 3-position of indole ring and N-carbamoylmethylpyridinium chloride (III), in the presence of sodium hydroxide or ammonium acetate. Reaction of 2-cinnamoylquinolines with III or with methyl- or quinolyl-carbonylmethylpyridinium chloride, in the presence of potassium carbonate or ammonium acetate, afforded (2-quinolyl) pyridine and (2-quinolyl) pyridin-2 (1H)-one derivatives.

収録刊行物

  • 薬学雑誌

    薬学雑誌 91 (9), 934-939, 1971

    公益社団法人 日本薬学会

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