Oxide-Phase Simulated Thermodynamics and Calculation of Thermochemical Properties of Compounds Auxiliary to Y–Ba–Cu–O High T<sub>c</sub> Superconductors<sup>*</sup>

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  • Šesták Jaroslav
    Division of Solid–State Physics, Institute of Physics of the Academy of Sciences of the Czech Republic, Cukrovarnicka 10, 16200 Praha 6, Czech Republic
  • Moiseev German K.
    Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Amundsen 101, GSP–812, 620219 Ekaterinburg, Russian Federation
  • Tzagareishvili Demna S.
    Institute of Metallurgy of the Georgian Academy of Sciences, Kasbegi 15, 380042 Tbilisi, Georgia

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  • Oxide-Phase Simulated Thermodynamics and Calculation of Thermochemical Properties of Compounds Auxiliary to Y-Ba-Cu-O High Tc Superconductors.

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説明

Evaluation methods for the estimation of standard enthalpy and entropy of formation, the temperature dependence of heat capacity and the temperature and heat of melting are shown for a generalised description of oxides. The calculation is applied to an actual simulation of the thermochemical data of real and hypothetical compounds for the following Y:Ba:Cu ratios: 123, 112, 213, 235, 133, 223, 135, 247, 124, 125, 516, 145, 146, 415, 132, 153, 312, 385, 163, 232, 143, 212, 122, 211, 121, 152, 131, 221, 321 and 142.

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