Stiff-chain behavior of poly(terephthalamide-p-benzohydrazide) in dimethyl sulfoxide.

DOI 被引用文献3件 参考文献20件 オープンアクセス

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説明

Fifteen fractionated samples of poly(terephthalamide-P-benzohydrazide) (PPAH) ranging in weight-average molecular weight from 2×103 to 6×104 were studied by light scattering, sedimentation equilibrium, and viscometry with dimethyl sulfoxide (DMSO) at 25°C as the solvent. The data obtained for the radius of gyration, the optical anisotropy factor, and the intrinsic viscosity showed the PPAH chain in DMSO to be semiflexible. Analysis of these data in terms of current theories for the Kratky–Porod wormlike chain gave 11.2±0.5 nm, 185±5 nm−1, 0.5 nm, and 2.1 for the persistence length, molar mass per unit contour length, diameter, and optical anisotropy [= 3(α1–α2)/(α1+2α2)] of the PPAH chain in DMSO, respectively. Here, α1 and α2 are, respectively, the longitudinal and transverse polarizabilities per unit contour length of the chain.

収録刊行物

  • Polymer Journal

    Polymer Journal 16 (7), 559-567, 1984

    The Society of Polymer Science, Japan

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詳細情報 詳細情報について

  • CRID
    1390282681265576320
  • NII論文ID
    130004767800
  • DOI
    10.1295/polymj.16.559
  • COI
    1:CAS:528:DyaL2cXlsFaltbw%3D
  • ISSN
    13490540
    00323896
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
    • OpenAIRE
  • 抄録ライセンスフラグ
    使用不可

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