Mean-Square Radius of Gyration of Poly(dimethylsiloxane) Chain with Side Groups.

  • Ma Haizhu
    Departmant of Mathematics-Physics, Zhejiang Institute of Education
  • Xu Jianmin
    Departmant of Physics, Hangzhou University

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説明

Using the rotational isomeric state theory, the unperturbed mean-square radius of gyration ⟨S2⟩ for the polymer chain considering the effect of a pair of side groups is derivated. If the spatial dimension (or the mass) of side groups and the mass difference of skeletal atoms are ignored, the expression is reduced to that of Flory and so forth. As an example, the numerical calculation of ⟨S2⟩ is executed for unperturbed poly(dimethylsiloxane). The molecular weight dependence of the mean-square radius of gyration is ⟨S2⟩⁄M=7.82×10−2 Å2 (g·mol)−1 which is in agreement with the experimental data. ⟨S2⟩⁄M=(7.7±0.3)×10−2 Å2 (g·mol)−1.

収録刊行物

  • Polymer Journal

    Polymer Journal 26 (7), 779-785, 1994

    The Society of Polymer Science, Japan

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詳細情報 詳細情報について

  • CRID
    1390282681266137728
  • NII論文ID
    130004768438
    30001927017
  • DOI
    10.1295/polymj.26.779
  • COI
    1:CAS:528:DyaK2cXkvVCnsLc%3D
  • ISSN
    13490540
    00323896
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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