Mean-Square Radius of Gyration of Poly(dimethylsiloxane) Chain with Side Groups.
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- Ma Haizhu
- Departmant of Mathematics-Physics, Zhejiang Institute of Education
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- Xu Jianmin
- Departmant of Physics, Hangzhou University
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説明
Using the rotational isomeric state theory, the unperturbed mean-square radius of gyration ⟨S2⟩ for the polymer chain considering the effect of a pair of side groups is derivated. If the spatial dimension (or the mass) of side groups and the mass difference of skeletal atoms are ignored, the expression is reduced to that of Flory and so forth. As an example, the numerical calculation of ⟨S2⟩ is executed for unperturbed poly(dimethylsiloxane). The molecular weight dependence of the mean-square radius of gyration is ⟨S2⟩⁄M=7.82×10−2 Å2 (g·mol)−1 which is in agreement with the experimental data. ⟨S2⟩⁄M=(7.7±0.3)×10−2 Å2 (g·mol)−1.
収録刊行物
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- Polymer Journal
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Polymer Journal 26 (7), 779-785, 1994
The Society of Polymer Science, Japan
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詳細情報 詳細情報について
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- CRID
- 1390282681266137728
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- NII論文ID
- 130004768438
- 30001927017
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- COI
- 1:CAS:528:DyaK2cXkvVCnsLc%3D
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- ISSN
- 13490540
- 00323896
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- 使用不可