Radical Polymerization and Copolymerization Behavior of N-Acryloyl N′-Cyanoacetohydrazide
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- Mokhtar Samia M.
- Department of Chemistry, Faculty of Women, Ain Shams University Heliopolis
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- El-Sabee Maher Z.
- Department of Chemistry, Faculty of Science, University of Cairo
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- Elkholy Said S.
- Department of Chemistry, Faculty of Science, University of Cairo
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- Sabaa Magdy W.
- Department of Chemistry, Faculty of Science, University of Cairo
書誌事項
- タイトル別名
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- Radical Polymerization and Copolymerization Behavior of N-Acryloyl N'-Cyanoacetohydrazide.
- Radical Polymerization and Copolymeriza
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The radical polymerization and copolymerization of N-acryloyl N′-cyanoacetohydrazide (ACAH), were carried in dimethyl formamide in presence of azobisisobutyronitrile as initiator and kinetic studies on the polymerization behavior of ACAH, conducted. Complex formation of ACAH monomer and polymer (PACAH) with Cu(II) and Fe(II) cations was investigated and the stability constant determined. The rate of copolymerization of ACAH with some conventional monomers named vinyl acetate, methyl methacrylate, and acrylonitrile was measured as a function of mole fractions of comonomers. The reactivity ratios (r1, r2) for the various investigated copolymer systems with the Q and e values of ACAH monomer were determined. The thermal gravimetric analysis of prepared polymer and copolymers with acrylonitrile was done.
収録刊行物
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- Polymer Journal
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Polymer Journal 29 (12), 964-969, 1997
The Society of Polymer Science, Japan
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詳細情報 詳細情報について
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- CRID
- 1390282681266510336
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- NII論文ID
- 10006273606
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- NII書誌ID
- AA00777013
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- COI
- 1:CAS:528:DyaK2sXotVGjtr0%3D
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- ISSN
- 13490540
- 00323896
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- NDL書誌ID
- 4371270
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可