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- Watanabe Toshio
- Department of Materials Science and Engineering, Yamagata University
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- Sakai Kazuyoshi
- Department of Materials Science and Engineering, Yamagata University
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- Sato Rikiya
- Department of Materials Science and Engineering, Yamagata University
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- Takeishi Makoto
- Department of Materials Science and Engineering, Yamagata University
書誌事項
- タイトル別名
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- Polymerization of Methyl Methacrylate Initiated by Arysulfinic Acids.
- Polymerization of Methyl Methacrylate I
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説明
Arylsulfinic acids such as benzenesulfinic acid (BSA) initiated the polymerization of methyl methacrylate (MMA) without oxidizing agents. Hydroquinone and 1,1-diphenyl-2-picrylhydrazyl had no inhibitory effect on the polymerization, indicating that the polymerization proceeded via a non-radical process. The rate of polymerization was found to be proportional to [BSA]0.98 and [MMA]0.99. The polymerization was greater in less polar solvents than in polar solvents. On the basis of the experimental results obtained, an ionic mechanism was proposed, in which a Michael-type addition of the arylsulfinic acid to MMA leads to the polymerization.
収録刊行物
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- Polymer Journal
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Polymer Journal 29 (6), 487-491, 1997
The Society of Polymer Science, Japan
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詳細情報 詳細情報について
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- CRID
- 1390282681266667136
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- NII論文ID
- 10006271841
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- NII書誌ID
- AA00777013
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- COI
- 1:CAS:528:DyaK2sXjvVKgsLk%3D
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- ISSN
- 13490540
- 00323896
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- NDL書誌ID
- 4240286
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可