Synthesis and Oxygen Permeability of Polynorbornene with Tosylate Side Chain Group.

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説明

A new oxygen/nitrogen separation membrane based on a polynorbornene with tosylate side chain group was synthesized using well-defined vinylidene ruthenium catalysts. The permeability, separation factor, diffusion and solubility coefficients of a polynorbornene membrane were studied. The introduction of tosylate group into the five-membered ring of the polynorbornene main chain results in increase of Tg and significant improvement in selectivity for O2/N2.

収録刊行物

  • Polymer Journal

    Polymer Journal 34 (2), 49-53, 2002

    The Society of Polymer Science, Japan

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