Synthesis of Novel Well-defined End-functional Macrophotoinitiator of Poly(ε-caprolactone) by Ring-opening Polymerization
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- Degirmenci Mustafa
- Harran University, Faculty of Science, Department of Chemistry
書誌事項
- タイトル別名
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- Synthesis of Novel Well-defined End-functional Macrophotoinitiator of Poly(.EPSILON.-caprolactone) by Ring-opening Polymerization
- Synthesis of Novel Well defined End functional Macrophotoinitiator of Poly イプシロン caprolactone by Ring opening Polymerization
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抄録
A new end-chain functional macrophotoinitiator of poly(ε-caprolactone) has been synthesized by controlled/living ring-opening polymerization (ROP) method. For this purpose, mono hydroxy functional a photoinitiator namely, 1-hydroxycyclohexyl phenyl ketone (HCPK), Irgacure 184, was used as the initiator for the stannous-2-ethylhexanoate (Sn(Oct)2) catalyzed living ring-opening polymerization of ε-caprolactone. The GPC and IR, H NMR, UV and fluorescence spectroscopic studies revealed that low-polydispersity poly(ε-caprolactone) with photoinitiator functionality at the end of the chain was obtained.
収録刊行物
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- Polymer Journal
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Polymer Journal 36 (7), 542-548, 2004
The Society of Polymer Science, Japan
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キーワード
詳細情報 詳細情報について
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- CRID
- 1390282681267580032
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- NII論文ID
- 10013342518
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- NII書誌ID
- AA00777013
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- ISSN
- 13490540
- 00323896
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- NDL書誌ID
- 7009091
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
