Co(AA)<sub>2</sub>-LiAlH<sub>4</sub>系触媒による一酸化炭素の液相水素化重合

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  • Hydrogenation of carbon monoxide to olefins catalyzed by bis(2,4-pentadionate)cobalt-lithium aluminum hydride system in liquid phase.

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説明

The catalytic activity and selectivity of the Co(AA)2 (AA=2, 4-pentadionate)-LiAlH4 system in tetrahydrofuran-tetralin for hydrogenation of CO were investigated in a 100ml batch reactor at 260°C. This catalyst system is active for hydrogenation of CO and produces linear hydrocarbons whose distribution has a maximum at less than C6. This system further shows a high selectivity for olefins, 85%. Supporting this system on silica gel causes a great change in the product distribution which has the maximum at C10.

収録刊行物

  • 石油学会誌

    石油学会誌 27 (3), 236-241, 1984

    公益社団法人 石油学会

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